Quantum Number Worksheet - Answer Key

 

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  1. Principal Quantum Number
    •  

    • Is represented by – n
    •  

    • Has values from ranging from – 1
    •  

    •  Indicates –  the size and energy level in which the electron is housed. 
      The bigger the n value, the further the electro is from the nucleus.
      •  

      • Degeneracy is when orbitals have the same value of n.

     

     

  2. Angular Momentum Quantum Number
    •  

    • Is represented by – l
    •  

    • Has values from ranging from – 0 (n-1)
    •  

    • Indicates – the type of orbital.
      •  

      • l = 0    s orbital
      • l = 1    p orbital
      • l = 2    d orbital
      • l = 3    f orbital


  3. Magnetic Quantum Number
    •  

    • Is represented by – ml
    •  

    • Has values from ranging from – ( –l + l)
    •  

    • Indicates – # of orbitals.
      •  

      •  l =0 (the s orbital) ml =0
        This means that there is only one s-orbital.

      •  

      •  l =1  (the p orbital) ml = (-1, 0, +1)
        Because there are 3 values of for m
        l there would be three p orbitals.
      •  

      • l =2   (the d orbital) ml = (-2, -1, 0, 1, 2)
        Because there are 5 values for m
        l there would be five d orbitals.
      •  

      • l = 3 (the f orbital)    ml = (-3, -2, -1, 0, 1, 2, 3)
        Because there are 7 values for  m
        l  there would be seven differently orientated f orbitals.

     

     

  4. Spin Quantum Number
    •  

    • Is represented by – ms
    •  

    • Has values from ranging from – (+½, - ½) 
    •  

    • Indicates – spin of an electron

     

     

  5. What is the Pauli Exclusion Principle?

    Only 2 electrons can be in a particular orbital and they must have opposite spin numbers.
  6.  

     

  7. Which of the following pairing of quantum numbers is invalid, why?
    •  

    • n=3, l =2, ml =2, ms = ½

      This set of quantum numbers is valid.  All values fit the required parameters.
    •  

    • n=4, l =3, ml =4, ms =- ½

      This set is invalid.  The value of m
      l cannot equal 4 if l = 3
    •  

    • n=0, l =0, ml =0, ms = -½

      This is an invalid set of quantum numbers because n cannot equal zero.
    •  

    • n=2, l =-1, ml =1, ms = ½

      This is an invalid set of quantum numbers because
      l cannot equal -1. 

     

     

  8. How many electrons can have the following designation?
    •  

    • 1p – None.
    •  

    • 6dxy2
    •  

    • 4f – 14
    •  

    • n=3 – 9